Answer / dr. a. bera, cdl

When not in use, the glass probe tip must be kept wet at all times to avoid the pH sensing membrane dehydration and the subsequent dysfunction of the electrode.
A glass electrode alone (i.e., without combined reference electrode) is typically stored immersed in an acidic solution of around pH 3.0. In an emergency, acidified tap water can be used, but distilled or deionised water must never be used for longer-term probe storage as the relatively ionless water "sucks" ions out of the probe membrane through diffusion, which degrades it.
Combined electrodes (glass membrane + reference electrode) are better stored immersed in the bridge electrolyte (often KCl 3 M) to avoid the diffusion of the electrolyte (KCl) out of the liquid junction.

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