POLYMER ENGINEERING - QUESTION 24.1 : The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18. The fraction of polymer chain X of 3 different monomers a, b and c in a polymer are Xa = 0.5, Xb = 0.3 and Xc = 0.2. (i) Calculate number average molecular weight by using the formula Ma Xa + Mb Xb + Mc Xc. (ii) Calculate weight average molecular weight by using the formula (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc). (iii) Calculate the polydispersity by using the answer in (ii) divided by answer in (i). (iv) If the molecular weight of repeat unit is 12, calculate the degree of polymerization by using the formula (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit).
POLYMER ENGINEERING - ANSWER 24.1 : (i) Number average molecular weight = Ma Xa + Mb Xb + Mc Xc = 14 x 0.5 + 16 x 0.3 + 18 x 0.2 = 15.4 kg / mol. (ii) Weight average molecular weight = (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc) = (14 x 0.5 x 14 + 16 x 0.3 x 16 + 18 x 0.2 x 18) / 15.4 = 15.558 kg / mol. (iii) Polydispersity = [ answer in (ii) ] / [ answer in (i) ] = 15.558 / 15.4 = 1.0103. (iv) Degree of polymerization = (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit) = (15.4 kg / mol) / (12 g / mol) = 1.283 k = 1283. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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QUANTUM COMPUTING - EXAMPLE 32.8 : In quantum computing, a quantum state is given by S = a | 00 > + b | 01 > + g | 10 > + d | 11 >. (a) Find S in term of | 0 > and | 1 > etc. (b) The probability of getting x is P(x). For S = 0.5 | 00 > + 0.5 | 01 > + 0.5 | 10 > + 0.5 | 11 >, find P(0) and P(1). Hint : P(00) + P(01) = P(0) = a x a + b x b, P(10) + P(11) = P(1) = g x g + d x d.
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ACCOUNTING AND FINANCIAL ENGINEERING - EXAMPLE 34.2 : (a) In the pricing of a coupon bond, the formula is : P = c / (1 + r) + (c + B) / [ (1 + r) (1 + r) ] for 2 years to maturity, where c = annual coupon payment (in dollars, not a percent), B = par value, P = purchase price. Five years ago someone bought a 20 year coupon bond and would like to get rid of it now : A coupon rate of 7 %, it matures in exactly 2 years, par value is $1000, current interest rate is 5 %. (i) Find the value of c. (ii) Find the value of r or interest rate. (iii) Find the value of P. (iv) Guess the formula for P when the maturity period is 3 years, if such formula for 1 year duration is P = (c + B) / (1 + r). (b) In lemma of Ito on a Forward, recall that a forward contract is priced at : ln F = ln S + rT. Find the value of F in 5 decimal points when S = $100, r = interest rate = 0.05 / year, T = duration = 1 year.
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ENGINEERING MATERIAL - EXAMPLE 12.2 : At 150 degree Celsius, a mixture of 40 wt % Sn and 60 wt % Pb present, forming phases of alpha and beta. Chemical composition of Sn at each phase : CO (overall) : 40 %, CA (alpha) : 11 %, CB (beta) : 99 %. (a) State 2 reasons for the existences of alpha and beta phases for the mixture of Sn - Pb at 150 degree Celsius. (b) By using Lever Rule, calculate the weight fraction of each phase for alpha, WA = Q / (P + Q) and beta, WB = P / (P + Q) where Q = CB - CO and P = CO - CA.
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