POLYMER ENGINEERING - QUESTION 24.1 : The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18. The fraction of polymer chain X of 3 different monomers a, b and c in a polymer are Xa = 0.5, Xb = 0.3 and Xc = 0.2. (i) Calculate number average molecular weight by using the formula Ma Xa + Mb Xb + Mc Xc. (ii) Calculate weight average molecular weight by using the formula (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc). (iii) Calculate the polydispersity by using the answer in (ii) divided by answer in (i). (iv) If the molecular weight of repeat unit is 12, calculate the degree of polymerization by using the formula (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit).
POLYMER ENGINEERING - ANSWER 24.1 : (i) Number average molecular weight = Ma Xa + Mb Xb + Mc Xc = 14 x 0.5 + 16 x 0.3 + 18 x 0.2 = 15.4 kg / mol. (ii) Weight average molecular weight = (Ma Xa Ma + Mb Xb Mb + Mc Xc Mc) / (Ma Xa + Mb Xb + Mc Xc) = (14 x 0.5 x 14 + 16 x 0.3 x 16 + 18 x 0.2 x 18) / 15.4 = 15.558 kg / mol. (iii) Polydispersity = [ answer in (ii) ] / [ answer in (i) ] = 15.558 / 15.4 = 1.0103. (iv) Degree of polymerization = (Ma Xa + Mb Xb + Mc Xc) / (molecular weight of repeat unit) = (15.4 kg / mol) / (12 g / mol) = 1.283 k = 1283. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
Is This Answer Correct ? | 0 Yes | 0 No |
What is the Import Procurement Cycle ? and what are the customization steps in SAP ?
what are lubricants using in compression.
What are the customization steps in sap?
hi.i m student of chemical engg. and studying in 5 th sem.how can i improve my technical knowledge..can u sugest me a link like book or any website..?
What is difference between Piping Standard & Piping Specification ?
what is the use of pressure filter?
types and working of compressor
Are fin tubes necessary for steam heating a liquid?
QUANTUM CHEMISTRY AND CHEMICAL ENGINEERING - EXAMPLE 31.7 : (a) The correct statement about both the average value of position (<x>) and momentum (<p>) of a 1-dimensional harmonic oscillator wavefunction is <x> = <p> = 1 - x. Find the value of x. (b) The probabilities of finding a particle around points A, B and C in the wavefunction y = f(x) are P(A), P(B) and P(C) respectively. Coordinates are A (3,5), B (4,-10) and C (6,7). Arrange P(A), P(B) and P(C) in term of a < b < c, when | y-coordinate | signifies the probability.
what is designing step of heat exchanger
How can you estimate a gas flow based on two pressure measurements?
What is a 'saltation velocity' and how is it used in designing pneumatic conveying systems?