Question 82 - (a) The Hyperion sewage plant in Los Angeles burns 8 million cubic feet of natural gas per day to generate power in United States of America. If 1 metre = 3.28084 feet, then how many cubic metres of such gas is burnt per hour? (b) A reservoir of natural gas produces 50 mole % methane and 50 mole % ethane. At zero degree Celsius and one atmosphere, the density of methane gas is 0.716 g / L and the density of ethane gas is 1.3562 mg / (cubic cm). The molar mass of methane is 16.04 g / mol and molar mass of ethane is 30.07 g / mol. (i) Find the mass % of methane and ethane in the natural gas. (ii) Find the average density of the natural gas mixture in the reservoir at zero degree Celsius and one atmosphere, by assuming that the gases are ideal where final volume of the gas mixture is the sum of volume of the individual gases at constant temperature and pressure. (iii) Find the average density of the natural gas mixture in the reservoir at zero degree Celsius and one atmosphere, by assuming that the final mass of the gas mixture is the sum of mass of the individual gases. Assume the gases are ideal where mole % = volume % at constant pressure and temperature.
Answer 82 - (a) 1 foot = (1 / 3.28084) metre = 0.3048 metre, 1 cubic foot = 0.3048 x 0.3048 x 0.3048 cubic metre = 0.0283 cubic metre, 8 million cubic feet = 8 million cubic feet x (0.0283 cubic metre / cubic feet) = 0.2264 million cubic metres. If 0.2264 million cubic metres of gas is burnt per day, then 0.2264 million / 24 = 9433 cubic metres of gas is burnt per hour. (b)(i) Let 50 mole of methane and 50 mole of ethane in the gas. Mass (g) = Mole (mol) x Molar Mass (g / mol), then mass of methane = 50 x 16.04 = 802 and mass of ethane = 50 x 30.07 = 1503.5. Total mass of natural gas = 802 g + 1503.5 g = 2305.5 g, then mass % of methane = (802 / 2305.5) x 100 = 34.786 % and mass % of ethane = 100 - 34.786 = 65.214 %. (ii) Density of methane gas = 0.716 g / L, density of ethane gas = 1.3562 mg / (cubic cm) = 1.3562 mg / mL = 1.3562 g / L. Volume (V) = Mass (m) / Density (r). Then V = m / r = 0.34786 m / 0.716 + 0.65214 m / 1.3562 = 0.9667 m, average density, r = m / (0.9667 m) = 1.0344 g / L. (ii) Mass (m) = Volume (V) x Density (r). Then m = Vr = 0.5V x 0.716 + 0.5V x 1.3562 = 1.0361V, average density, r = 1.0361V / V = 1.0361 g / L. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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A concentric, counter-current heat exchanger is used to cool lubricating oil. Water is used as the coolant. The mass flow rate of oil into the heat exchanger is 0.1 kg / s = FO. For oil, the inlet temperature TIO = 100 degree Celsius and the outlet temperature TOO = 55 degree Celsius. For water, the inlet temperature TIW = 35 degree Celsius and the outlet temperature TOW = 42 degree Celsius. What is the mass flow rate of water in kg / s, FW needed to maintain these operating conditions? Constant for heat capacity of oil is CO = 2131 J /(kg K) and for water is CW = 4178 J /(kg K). Use the equation (FO)(CO)(TIO – TOO) = (FW)(CW)(TOW – TIW).
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Question - Chemical Engineering Material - In crystal material, hexagonal crystal system could form 4-digit index in certain direction of solid. For [1(-1)0] direction in the hexagonal crystal systems of particular catalyst applied in fume removal of incinerator, what is the four-digit index for this direction? Hint : The transformation equations between the 3-digit [h’k’l’] and the 4-digit [hkil] indices are : h = (1/3) (2h’ – k’); i = - (h + k); k = (1/3) (2k’ – h’); l = l’. A. [(-1)100] B. [1(-1)00] C. [(-1)000] D. [00(-1)(-1)] E. [(-1)0(-1)0]
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MASS TRANSFER - EXAMPLE 4.2 : In a non-dilute absorber, graphical method is used to represent the process. In an X - Y coordinate system, X-axis represents mole of carbon dioxide / mole of water and Y axis represents mole of carbon dioxide / mole of nitrogen. The inlet gas stream consists of 8 mol % of carbon dioxide in nitrogen. (a) Find the S / G minimum as a slope that goes through the point (0, 0.0304) and (0.0000488, 0.086957). (b) Find the actual slope of operating line when it is 1.5 times the S / G minimum! (c) Find the value of x for inlet gas stream when y = 1640 x, y is mole fraction of carbon dioxide in nitrogen.
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