BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.6 : In infrared spectrum, one of the factors affecting peak location is the mass of the atoms. The stretching frequency of a bond connected to a lighter atom will be greater than the same bond connected to a heavier atom. (a) For halogens like florine (F), chlorine (Cl), bromine (Br), iodine (I) and astatine (At), what is their IUPAC group number? Hint : The proton numbers for F, Cl, Br, I and At are 9, 17, 35, 53 and 85 respectively. (b) For the compounds of H-F, H-Cl, H-Br, H-I and H-At, which one has the lowest stretching frequency and which one has the highest stretching frequency? State the reasons.
BIOCHEMICAL ENGINEERING INSTRUMENTATION - ANSWER 29.6 : (a) 17. (b) Lowest stretching frequency : H-At. Highest stretching frequency : H-F. Reasons : F has the lowest proton number 9 and At has the highest proton number 85. For the compound of H-X, the stretching frequency of the bond decreases when the mass of X increases and vice versa. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 106 - In a wavefunction, let P(x) = A cos kx + B sin kx. By using the boundary conditions of x = 0 and x = l, where P(0) = P(l) = 0, prove by mathematical calculation that P(x) = B sin (npx / l) where p = 22 / 7 approximately, n is a rounded number. A, B and k are constants.
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Three solid objects of the same material and of equal mass – a sphere, a cylinder (length = diameter) and a cube – are at 5000C initially. These are dropped in a quenching bath containing a large volume of cooling oil each attaining the bath temperature eventually. The time required for 90% change of temperature is smallest for a) cube b) cylinder c) sphere d) equal for all the three whyyyyyyy???????
ACCOUNTING AND FINANCIAL ENGINEERING - EXAMPLE 34.22 : An engineering company intends to produce a small piece of biochemical instrument for sales. Let A = overall fixed cost of production, B = variable cost of production per unit, C = selling price per unit, D = quantity of unit produced. Breakeven Analysis is used where revenue = cost. (a) Explain the role of Breakeven Analysis by using A, B, C and D. (b) Find the value of Contribution Margin in term of A, B, C and / or D. (c) At the breakeven point where revenue = cost, derive an equation of D as a function of A, B and C.
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7 Answers CPCL, Kelvin Power Station,
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REACTION ENGINEERING - EXAMPLE 13.2 : A batch reactor is designed for the system of the irreversible, elementary liquid-phase hydration of butylene oxide that produces butylene glycol. At the reaction temperature T = 323 K, the reaction rate constant is k = 0.00083 L / (mol - min). The initial concentration of butylene oxide is 0.25 mol / L = Ca. The reaction is conducted using water as the solvent, so that water is in large excess. (a) Let the molecular weight of water is 18 g / mol and the mass of 1 kg in 1 L of water, calculate the molar density of water, Cb in the unit of mol / L. (b) Determine the final conversion, X of butylene oxide in the batch reactor after t = 45 min of reaction time. Use the formula X = 1 - 1 / exp [ kt (Cb) ] derived from material balance. (c) Find the equation of t as a function of X.
List the advantages and disadvantages of a pfr?
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How can one quickly estimate the additional pressure drop to be introduced with more tube passes?
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