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At 150 degree Celsius, a mixture of 40 wt % Sn and 60 wt % Pb present, forming phases of alpha and beta. Chemical composition of Sn at each phase : CO (overall) : 40 %, CA (alpha) : 11 %, CB (beta) : 99 %. (a) State 2 reasons for the existences of alpha and beta phases for the mixture of Sn – Pb at 150 degree Celsius. (b) By using Lever Rule, calculate the weight fraction of each phase for alpha, WA = Q / (P Q) and beta, WB = P / (P Q) where Q = CB – CO and P = CO – CA.
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Question 76 - Let C% be the fractional crystallinity, Rs = density of sample, Ra = density of amorphous form and Rc = density of crystalline form. In a polymer, these unknowns could be related by the equation C% = (Rc / Rs) (Rs - Ra) / (Rc - Ra). (a) Find the equation of Rc as a function of C%, Rs and Ra. (b) Two samples of a polymer, C and D exist. For sample C, C% = 0.513 when Rs = 2.215 unit. For sample D, C% = 0.742 when Rs = 2.144 unit. Both samples C and D have the same values of Ra and Rc. Find the values of Ra and Rc in 6 decimal places.
Question 104 - In photoelectrical effect analysis of quantum chemistry, let E = kinetic energy of electron, p = intensity of UV light, f = frequency of UV light. According to Classical Theory, E = c for all values of f, E = mp. According to Quantum Theory, E = c for all values of p, E = mf + c. In a graph, m and c are constants where m is slope and c is y intercept. If m = 2 and c = 3 with similar value of E : (a) find the value of p according to Classical Theory; (b) find the value of f according to Quantum Theory.
Question 83 - The United States of America Energy Information Administration reports the following emissions in million metric tons of carbon dioxide in the world for year 2012 : Natural gas : 6799, petroleum : 11695, coal : 13787. Coal-fired electric power generation emits around 2000 pounds of carbon dioxide for every megawatt hour generated, which is almost double the carbon dioxide released by a natural gas-fired electric plant per megawatt hour generated. If 1 metric ton = 1000 kg and 1 pound = 0.4536 kg, estimate the total energy generated by natural gas in the world for year 2012, in gigawatt hour.
CHEMICAL MATERIAL BALANCE - EXAMPLE 2.5 : In a non-dilute absorber, the inlet gas stream consists of 8 mol % carbon dioxide in nitrogen. By contact with room temperature water at atmospheric pressure, 65 % of the carbon dioxide from a gas stream has been removed. (a) Find the mole ratio of carbon dioxide and nitrogen gases at inlet and outlet gas streams. (b) The Henry's Law provides y = 1640 x for carbon dioxide in water. Find the mole ratio when x = 0.0000427. Mole ratio is y / (1 - y) for y.
A cylinder with a movable piston contains 0.1 mole of a monoatomic ideal gas. The piston moves through state a, b and c. The heat Q, changes from state c to a is 685 J. The work W, changes from state c to a is -120 J. The work, W performed from state a to b then to c is 75 J. By using the first law of thermodynamic, U = Q W where U is the internal energy : (a) Determine the change in internal energy between states a and c. (b) Is heat added or removed from the gas when the gas is taken along the path abc? (c) Calculate the heat added or removed when the gas is taken along the path abc?
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