REACTION ENGINEERING - EXAMPLE 13.2 : A batch reactor is designed for the system of the irreversible, elementary liquid-phase hydration of butylene oxide that produces butylene glycol. At the reaction temperature T = 323 K, the reaction rate constant is k = 0.00083 L / (mol - min). The initial concentration of butylene oxide is 0.25 mol / L = Ca. The reaction is conducted using water as the solvent, so that water is in large excess. (a) Let the molecular weight of water is 18 g / mol and the mass of 1 kg in 1 L of water, calculate the molar density of water, Cb in the unit of mol / L. (b) Determine the final conversion, X of butylene oxide in the batch reactor after t = 45 min of reaction time. Use the formula X = 1 - 1 / exp [ kt (Cb) ] derived from material balance. (c) Find the equation of t as a function of X.
REACTION ENGINEERING - ANSWER 13.2 : (a) Cb = (1000 g / L) / (18 g / mol) = 55.556 mol / L. (b) X = 1 - 1 / exp [ kt (Cb) ] = 1 - 1 / exp (0.00083 x 45 x 55.556) = 0.8744. (c) X = 1 - 1 / exp [ kt (Cb) ], 1 / exp [ kt (Cb) ] = 1 - X, exp [ kt (Cb) ] = 1 / (1 - X), (Cb) kt = ln [ 1 / (1 - X) ], t = 1 / [ k (Cb) ] ln [ 1 / (1 - X) ] = ln [ 1 / (1 - X) ] / [ k (Cb) ]. The answer is given by Kang Chuen Tat; PO Box 6263, Dandenong, Victoria VIC 3175, Australia; SMS +61405421706; chuentat@hotmail.com; http://kangchuentat.wordpress.com.
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Question 35 – A mixture consists of benzene (B), toluene (T) and xylene (X). At a temperature of 353 K, the data of vapor pressures : B : 754.12, T : 289.71, X : 91.19. Unit is mm Hg. The pressure P is 0.5 atm. The value of k for each substance is k = (vapor pressure) / P. (a) Calculate k for B, T and X. Let L / V = 0.65. (b) By using the equation V = F / [ (L / V) + 1 ], find the value of V when F = 100, then what is the value of L?
BIOCHEMICAL ENGINEERING INSTRUMENTATION - EXAMPLE 29.4 : The resolution of separation, Rs for chromatography is given by the formula Rs = (difference in retention time) / (average width at the base). In a chromatogram, 3 peaks a, b and c are found. Average widths W at the bases of the solutes are : Wa = 20 s, Wb = 40 s, Wc = 30 s. Resolutions of separation, Rs for solutes b and c in comparison to a are 2 and 4 respectively. The differences in retention times T for b and c in comparison to a are (Tb - Ta) and (Tc - Ta), Ta = Tc - Tb : (a) Form 2 equations involving Rs as a function of Wa, Wb, Wc, Ta, Tb and Tc. (b) Find the values of Ta, Tb and Tc.
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NATURAL GAS ENGINEERING - QUESTION 26.3 : The United States of America Energy Information Administration reports the following emissions in million metric tons of carbon dioxide in the world for year 2012 : Natural gas : 6799, petroleum : 11695, coal : 13787. Coal-fired electric power generation emits around 2000 pounds of carbon dioxide for every megawatt hour generated, which is almost double the carbon dioxide released by a natural gas-fired electric plant per megawatt hour generated. If 1 metric ton = 1000 kg and 1 pound = 0.4536 kg, estimate the total energy generated by natural gas in the world for year 2012, in gigawatt hour.
GENETIC ENGINEERING - EXAMPLE 27.3 : (a) Male with genotype GGmm and phenotype gray wingless mates with female with genotype ggMM and phenotype black winged in fruit flies. G is dominant to g in color. M is dominant to m in wing shape. If the actual distribution of the second generation of the fruit flies was as follow : 890 gray wingless, 900 black winged, 115 gray winged, 95 black wingless, calculate the recombination frequency between the two genes and distance in recombination units. Let 1 map unit = 1 % recombination. (b) A DNA molecule has 180 base pairs and 20 % adenine. How many cytosine nucleotides are present in this molecule of DNA?
COMPUTER PROGRAMMING FOR ENGINEERS - EXAMPLE 17.3 : (a) The byte is the basic building block of computer data used in chemical engineering process simulation where 16 bits make a word, 4 bits make a nibble, 32 bits make a quad word and 8 bits make a byte. Then how many nibbles are there in a megabytes? (b) In computer data items, let : 1 bit - counts from 0 to 1, 8 bits - counts from 0 to 255, 16 bits - counts from 0 to A. What is the value of A? (c) In a binary system of 4 bits, if 1100 = 12, 1101 = 13, 1110 = 14, 1111 = 15, B = 16, then guess the value of B. (d) By using any form of tools, find the exact value of 2 power 64 or 2^64.
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