What are the criteria’s involved in choosing mass balances for components?


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POLYMER ENGINEERING - QUESTION 24.3 : The molecular weights M in kg / mol of 3 different monomers a, b and c in a polymer are Ma = 14, Mb = 16 and Mc = 18, with their respective quantities in N units having the ratio of Na : Nb : Nc = 2 : 3 : 5. (a) Find the numerical average molecular weight of the polymer by using the formula (Ma Na + Mb Nb + Mc Nc) / (Na + Nb + Nc). (b) Find the weighted average molecular weight of the polymer by using the formula (Ma Na Ma + Mb Nb Mb + Mc Nc Mc) / (Ma Na + Mb Nb + Mc Nc). (c) Calculate the polydispersity Q by using the answer in (b) divided by answer in (a). (d) Find the volumetric average molecular weight of the polymer by using the formula (Ma Na Ma Ma + Mb Nb Mb Mb + Mc Nc Mc Mc) / (Ma Na Ma + Mb Nb Mb + Mc Nc Mc). (e) Estimate the polydispersity Q by using the answer in (d) divided by answer in (b).

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UNIT OPERATION - EXAMPLE 9.3 : In the distillation of binary systems by Mc Cabe Thiele method, the equation for the line of top section is given by y = [ R / (R + 1) ] x + XD / (R + 1). 2 points on the line are (0.99, 0.99) and (0, 0.36). Find the reflux ratio of R and XD.

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